肾上腺素电氧化过程的快速扫描循环伏安研究

以快速循环伏安法为主要手段,研究了肾上腺素电化学氧化反应机理.肾上腺素在1 m ol•dm－3 H2SO4中的电化学氧化反应,具有扩散控制的基本特征,并伴随着电活性质粒的 弱吸附现象.在快速电势扫描条件下,肾上腺素电氧化过程遵从EC反应机理.当肾上腺素浓度低于1.00×10－3 mol•dm－3时,吸附现象的特征趋于显现出来;在快速电势扫描速率下,电活性质粒吸附的特征更加明显.结合表面伏安法分析,估算了肾上腺素电氧化过程的传递系数α=0.264.电化学反应速率常数ks=31.81 s－1.     

Li2+2xZn1-xSiO4水基溶胶-凝胶法合成及其离子导电性

用水基溶胶凝胶法制备了锂离子导体Li_2+2xZn_1-xSiO₄(0≤x≤0.5)。实验中对干凝胶的热稳定性进行了TG-DTG分析。XRD谱结果表明形成了与Li₃PO₄结构相关的固溶体Li_2+2xZn_1-xSiO₄。TEM结果则显示晶粒尺寸为50nm左右,并应用交流阻抗谱技术进行了样品烧结体的电性能测试。     

稀土固体超强酸SO42-/TiO2/La3+催化合成丁酸异戊酯

The synthesis of isoamyl butyrate with isoamyl alcohol and butyric acid as reactants and rare-earth solid superacid SO₄^2-/TiO₂/La³⁺ as catalyst had been studied.The influent actors of reaction were investigated.The results showed that the appropriate conditions should be: Weight of catalyst was 0.5g (weight of butyric acid if 0.2mol); molar ratio of isoamyl alcohol to butyric acid was 1.8: 1; reaction time was 2.0 h; the taking water reagent (Toluene) was 15mL.The yield of isoamyl butyrate was about 99.0%.     

有机溶剂对酶催化活性和选择性的影响

有机溶剂中酶的结构与功能与在水中有很大的不同, 通过调整反应介质可系统地改善酶针对目标反应的活性和选择性。重点阐述了溶剂对酶催化反应的活性和选择性的影响及其控制策略, 给出了酶催化选择性的热力学预测模型。     

Studies on Non-isothermal Kinetics of the Thermal Decomposition of Eu2(BA)6(bipy)2

The thermal decomposition of Eu₂(BA)₆(bipy)₂ (BA=C₂H₅N^– ₂, benzoate; bipy=C₁₀H₈N₂, 2,2'-bipyridine)and its kinetics were studied under the non-isothermal condition by TG-DTG, IR and SEM methods. The kinetic parameters were obtained from analysis of the TG-DTG curves by the Achar method, the Madhusudanan-Krishnan-Ninan (MKN) method, the Ozawa method and the Kissinger method. The most probable mechanism function was suggested by comparing the kinetic parameters. The kinetic equation for the first stage can be expressed as: dα/dt=Aexp(–E/RT)3(1–α)^2/3. This revised version was published online in August 2006 with corrections to the Cover Date.     

On simple modules over conformal Galilei algebras

We study irreducible representations of two classes of conformal Galilei algebras in 1-spatial dimension. We construct a functor which transforms simple modules with nonzero central charge over the Heisenberg subalgebra into simple modules over the conformal Galilei algebras. This can be viewed as an analogue of oscillator representations. We use oscillator representations to describe the structure of simple highest weight modules over conformal Galilei algebras. We classify simple weight modules with finite dimensional weight spaces over finite dimensional Heisenberg algebras and use this classification and properties of oscillator representations to classify simple weight modules with finite dimensional weight spaces over conformal Galilei algebras.     

Irreducible Harish-Chandra modules over extended Witt algebras

Let d be a positive integer, $A={\mathbb{C}} [t_{1}^{\pm1},\ldots ,t_{d}^{\pm1}]$ be the Laurent polynomial algebra, and $W=\operatorname{Der} (A)$ be the derivation Lie algebra of A. Then we have the semidirect product Lie algebra W?A which we call the extended Witt algebra of rank d. In this paper, we classify all irreducible Harish-Chandra modules over W?A with nontrivial action of A.     

赋β-范空间中单位球面间的等距算子的线性延拓

本文得到了等距映射的线性延拓的一般结果:设E,F是赋范(或β-严格凸赋β-范)线性空间,若V_0:S_1(E)→S_1(F)是等距,且对任意的x,y∈S_1(E),有‖V_0x-|(?)|V_0y‖≤‖x-|(?)|y‖,(?)∈R,则V_0必可延拓到全空间上等距算子(或线性等距算子)。特别,当E,F是赋范线性空间,V_0是满射或F为严格凸空间时,则V_0必可延拓为全空间的线性等距算子,从而推广了文[3～5]中的相应结果。     

新水溶性卟啉季铵盐的合成及与锌的显色反应研究

合成了-种新型水溶性卟啶卟啉季铵盐即溴化5-[(4-N-芐基)吡啶基]10,15,20-(4-N-吡啶基)卟啉,研究了该试剂与锌的显色反应.在pH2.5的邻苯二甲酸氢钾-盐酸缓冲溶液中,形成了配位比为1:1的配合物,基最大吸收波长λ=424nm,表现摩尔吸光系数ε=2.03×105L·mol-1·cm-1.在0-1.2μg/10mL范围内吸光度与锌质量浓度关系符合比耳定律,该法灵敏度高、选择性好.本法应用于环境水试样中痕量锌离子的分析,结果令人满意.     

广义p-Laplace算子相关的非线性边值问题解的存在性

本文首先把p-Laplace算子推广为广义p-Laplace算子,然后利用非线性增生映射值域的扰动理论研究了与广义p-Laplace算子相关的具有牛曼边值的非线性椭圆问题在LP(Ω)空间中解的存在性,其中2≤p< ∞．本文所讨论的方程及所用的方法是对以往一些工作的补充和延续．